Kinetics of Sulfur, Vanadium and Nickel Removal from Basra Crude Oil Hydro Treating
الشريط الجانبي للمقالة
محتوى المقالة الرئيسي
الملخص
Basra crude oil was hydro treated in trickle–bed reactor using cobalt – molybdenum alumina as a Catalyst. The reaction range temperatures was598 – 648 k, while LHSV was 0.7 – 2 hr-1. The pressure and H2/Oil for all experiments keep constant at 3Mpa and 300 L/L respectively. Desulphurization and demutualization kinetics were studied and found that the kinetics of sculpture removal is of first – order, and the kinetic of vanadium and nickel removal is of second – order. Activation energy were calculated and their value are 24.03, 745.86, 63.90 KJ / mole, respectively for sculpture, vanadium, and nickel.
المقاييس
تفاصيل المقالة
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المراجع
Speight J. G.; ((The Desulphurization of Heavy Oils and Residue)), (1981).
Mohammed A. A. and Hankishe K., Fuel, Vol. (64), 621-924, (1985). DOI: https://doi.org/10.1016/0016-2361(85)90144-9
Henry H. C. and Gilbert J. B.; Ind. Eng. Chem. Process Des. Dev., 12, 328, (1973). DOI: https://doi.org/10.1021/i260047a019
Yui S. M. and Sanford E. C., Ind. Eng. Chem. Res., Vol. (28), 1278 – 1284, (1989). DOI: https://doi.org/10.1021/ie00093a002
Abbas A. S., M.SC. Thesis university of Baghdad, College of Engineering, Chem. Eng. Department (1999).
Arey F. Jr., Black well N. E. and Reichle A. D.; Seventh world petroleum congress, 4, 167, (1968) .
A, reff H. A., M.SC. Thesis University of Tikrit, College of Engineering, Chem. Eng. Department (2001).
Mohammed A. A., Karim H. N. and Ihsan N. A., Fuel, Vol. (67), 36-39 (1988) . DOI: https://doi.org/10.1016/0016-2361(88)90009-9
Antonio, Iannlbello A., Marengo S., Burgio G., Baldi G., Sicardl S. and Specchil V., Ind. Eng. Chem. Process Des. Dev., 24(3), 531 – 537, (1985). DOI: https://doi.org/10.1021/i200030a003
Woodle R. A., William B. and Chandler J., Ind. and Eng. Chem., 44(11), 2591 – 2596 (1952). DOI: https://doi.org/10.1021/ie50515a035
Paraskos J. A., Frayer J. A. and Shah Y. T., Ind. Eng. Chem. Process Des. Dev., 14(3), 315 – 322 (1975). DOI: https://doi.org/10.1021/i260055a021
Ali L. H. and Abdul-Karim E.; ((The Oil, Origin, Composition and Technology )), Mosul – Iraq (1986).
Mc culloch D. C., In Applied Industrial Catalysis, 1(69), (1983). DOI: https://doi.org/10.1016/S0033-3506(83)80032-8
Weisser O. and Landa. S., Pergamon Press, (1973).