Kinetics of Sulfur, Vanadium and Nickel Removal from Basra Crude Oil Hydro Treating
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Abstract
Basra crude oil was hydro treated in trickle–bed reactor using cobalt – molybdenum alumina as a Catalyst. The reaction range temperatures was598 – 648 k, while LHSV was 0.7 – 2 hr-1. The pressure and H2/Oil for all experiments keep constant at 3Mpa and 300 L/L respectively. Desulphurization and demutualization kinetics were studied and found that the kinetics of sculpture removal is of first – order, and the kinetic of vanadium and nickel removal is of second – order. Activation energy were calculated and their value are 24.03, 745.86, 63.90 KJ / mole, respectively for sculpture, vanadium, and nickel.
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References
Speight J. G.; ((The Desulphurization of Heavy Oils and Residue)), (1981).
Mohammed A. A. and Hankishe K., Fuel, Vol. (64), 621-924, (1985). DOI: https://doi.org/10.1016/0016-2361(85)90144-9
Henry H. C. and Gilbert J. B.; Ind. Eng. Chem. Process Des. Dev., 12, 328, (1973). DOI: https://doi.org/10.1021/i260047a019
Yui S. M. and Sanford E. C., Ind. Eng. Chem. Res., Vol. (28), 1278 – 1284, (1989). DOI: https://doi.org/10.1021/ie00093a002
Abbas A. S., M.SC. Thesis university of Baghdad, College of Engineering, Chem. Eng. Department (1999).
Arey F. Jr., Black well N. E. and Reichle A. D.; Seventh world petroleum congress, 4, 167, (1968) .
A, reff H. A., M.SC. Thesis University of Tikrit, College of Engineering, Chem. Eng. Department (2001).
Mohammed A. A., Karim H. N. and Ihsan N. A., Fuel, Vol. (67), 36-39 (1988) . DOI: https://doi.org/10.1016/0016-2361(88)90009-9
Antonio, Iannlbello A., Marengo S., Burgio G., Baldi G., Sicardl S. and Specchil V., Ind. Eng. Chem. Process Des. Dev., 24(3), 531 – 537, (1985). DOI: https://doi.org/10.1021/i200030a003
Woodle R. A., William B. and Chandler J., Ind. and Eng. Chem., 44(11), 2591 – 2596 (1952). DOI: https://doi.org/10.1021/ie50515a035
Paraskos J. A., Frayer J. A. and Shah Y. T., Ind. Eng. Chem. Process Des. Dev., 14(3), 315 – 322 (1975). DOI: https://doi.org/10.1021/i260055a021
Ali L. H. and Abdul-Karim E.; ((The Oil, Origin, Composition and Technology )), Mosul – Iraq (1986).
Mc culloch D. C., In Applied Industrial Catalysis, 1(69), (1983). DOI: https://doi.org/10.1016/S0033-3506(83)80032-8
Weisser O. and Landa. S., Pergamon Press, (1973).