دراسة ميكانيكية تفاعل ثاني اوكسيد الكاربون مع السوائل العضوية الملزمة
الشريط الجانبي للمقالة
محتوى المقالة الرئيسي
الملخص
السوائل العضوية الملزمة هي قاعدة قوية من الاميدين تستخدم لالتقاط CO2 . لحد الآن، لا توجد بيانات معروفة عن حركية تفاعل
ثاني أكسيد الكربون مع ) DBN (. في هذه الورقة، تم دراسة آلية التفاعل والحركية باستخدام خلية تفاعل مع تركيز (DBN) ( 2
– 2.9 مولاري( عند درجة حرارة الغرفة. تم وصف مسار التفاعل باستخدام زيوترن والآلية الجزئية. من البيانات الحركية ل
DBN بتراكيز (2 - 2.9) M ، وجد أن عملية الامتصاص تحدث في نظام تفاعل سريع مع حركية تفاعل من الدرجة الثانية مع
DBN/MDEA و الدرجة الأولى مع CO2. اضافة الى ذلك فان امتصاص غاز CO2 كان ) ثا . كيلومول م⁄ 2×10−5−2.8 × 10−5 ( عند تركيز DBN ( 2.9 – 2 مولاري(. اخيرا، كما هو معروف فان نظام DBN/MDEA/1-Pentanol/CO2 سهل التحول ومن الممكن استخدامه لالتقاط CO2 وتطبيقات اخرى تحتاج لتغير السريع للوسط من لاايوني الى
ايوني.
المقاييس
تفاصيل المقالة
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
THIS IS AN OPEN ACCESS ARTICLE UNDER THE CC BY LICENSE http://creativecommons.org/licenses/by/4.0/
##plugins.generic.plaudit.displayName##
المراجع
Herzog HJ. Peer reviewed: what future for carbon capture and sequestration?: ACS Publications; 2001.
Herzog HJ. Scaling up carbon dioxide capture and storage: From megatons to gigatons. Energy Economics 2011;33:597-604.
Wiheeb AD, Shamsudin IK, Ahmad MA, Murat MN, Kim J, Othman MR. Present technologies for hydrogen sulfide removal from gaseous mixtures. Reviews in Chemical Engineering 2013;29:449-70.
Wiheeb A, Helwani Z, Kim J, Othman M. Pressure swing adsorption technologies for carbon dioxide capture. Separation & Purification Reviews 2016;45:108-21.
Heldebrant DJ, Yonker CR, Jessop PG, Phan L. Organic liquid CO2 capture agents with high gravimetric CO2 capacity. Energy & Environmental Science 2008;1:487-93.
Heldebrant DJ, Koech PK, Rainbolt JE, Zheng FR. CO2-binding organic liquids, an integrated acid gas capture system. Energy Procedia 2011;4:216-23.
Peeters A, Faaij A, Turkenburg W. Techno-economic analysis of natural gas combined cycles with post-combustion CO2 absorption, including a
detailed evaluation of the development potential. International Journal of Greenhouse Gas Control 2007;1:396-417.
Heldebrant DJ, Yonker CR, Jessop PG, Phan L. CO2-binding organic liquids (CO2 BOLs) for post-combustion CO2 capture. Energy Procedia 2009;1:1187-95.
Jessop PG, Heldebrant DJ, Li X, Eckert CA, Liotta CL. Green chemistry: Reversible nonpolar-to-polar solvent. Nature 2005;436:1102.
Öztürk MÇ, Ume CS, Alper E. Reaction Mechanism and Kinetics of 1, 8‐Diazabicyclo [5.4. 0] undec‐7‐ene and Carbon Dioxide in Alkanol Solutions. Chemical Engineering&Technology 2012;35:2093-8.
Ozturk MC, Orhan OY, Alper E. Kinetics of carbon dioxide binding by 1, 1, 3, 3-tetramethylguanidine in 1-hexanol. International Journal of Greenhouse Gas Control 2014;26:76-82.
YÜKSEL Ö, ÖZTÜRK MÇ, ŞEKER A, ALPER E. Kinetics and performance studies of a switchable solvent TMG (1, 1, 3, 3-tetramethylguanidine)/1-propanol/carbon
dioxide system. Turkish Journal of Chemistry 2015;39:13-24.
Mathias PM, Afshar K, Zheng F, Bearden MD, Freeman CJ, Andrea T, et al. Improving the regeneration of CO2-binding organic liquids with a polarity change. Energy & Environmental Science 2013;6:2233-42.
Caplow M. Kinetics of carbamate formation and breakdown. Journal of the American Chemical Society 1968;90:6795-803.
Danckwerts P. The reaction of CO2 with ethanolamines. Chemical Engineering Science 1979;34:443-6.
Sutar PN, Jha A, Vaidya PD, Kenig EY. Secondary amines for CO2 capture: A kinetic investigation using N-ethylmonoethanolamine. Chemical engineering Journal 2012;207:718-24.
Ali SH. Kinetics of the reaction of carbon dioxide with blends of amines in aqueous media using the stopped‐flow technique. International Journal of Chemical Kinetics 2005;37:391-405.
Vaidya PD, Kenig EY. A Study on CO2 Absorption Kinetics by Aqueous Solutions of N, N‐Diethylethanolamine and N‐Ethylethanolamine. Chemical Engineering&Technology 2009;32:556-63.
Orhan OY, Alper E. Kinetics of carbon dioxide binding by promoted organic liquids. Chemical Engineering & Technology 2015;38:1485-9.
Ozkutlu M, Orhan OY, Ersan HY, Alper E. Kinetics of CO2 capture by ionic liquid—CO2 binding organic liquid dual systems. Chemical Engineering and Processing: Process Intensification 2016;101:50-5.
Ume CS, Ozturk MC, Alper E. Kinetics of CO2 absorption by a blended aqueous amine solution. Chemical Engineering & Technology 2012;35:464-8.
Crooks JE, Donnellan JP. Kinetics and mechanism of the reaction between carbon dioxide and amines in aqueous solution. Journal of the Chemical Society, Perkin Transactions 2 1989:331-3.
Orhan OY, Alper E. Kinetics of reaction between CO2 and ionic liquid-carbon dioxide binding organic liquid hybrid systems: Analysis of gas-liquid absorption and stopped flow experiments. Chemical Engineering Science 2017;170:36-47.
Sada E, Kumazawa H, Han Z, Matsuyama H. Chemical kinetics of the reaction of carbon dioxide with ethanolamines in nonaqueous solvents. AIChE Journal 1985;31:1297-303.
Vaidya PD, Kenig EY. Termolecular Kinetic Model for CO2‐Alkanolamine Reactions: An Overview. Chemical Engineering& Technology 2010;33:1577-81.
Versteeg GF, Van Swaaij WP. Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkanolamine solutions. Journal of Chemical & Engineering Data 1988;33:29-34.
Orhan OY, Tankal H, Kayi H, Alper E. Kinetics of CO2 capture by carbon dioxide binding organic liquids: Experimental and molecular modelling studies. International Journal of Greenhouse Gas Control 2016;49:379-86.
Tankal H, Orhan ÖY, Alper E, Özdoğan T, Kayi H. Experimental and theoretical investigation of the reaction between CO $ _ {2} $ and carbon dioxide binding organic liquids. Turkish Journal of Chemistry 2016;40:706-19.
Alper E. Reaction mechanism and kinetics of aqueous solutions of 2-amino-2-methyl-1-propanol and carbon dioxide. Industrial & Engineering Chemistry Research 1990;29:1725-8.
Li J, Henni A, Tontiwachwuthikul P. Reaction kinetics of CO2 in aqueous ethylenediamine, ethyl ethanolamine, and diethyl monoethanolamine solutions in the temperature range of 298− 313 K, using the stopped-flow technique. Industrial & Engineering Chemistry Research 2007;46:4426-34.